METHOD FOR AROMATIC AMINE PRODUCTION IN PRESENCE OF PALLADIUM COMPLEX INCLUDING FERROCENYLBIPHOSPHINIC LIGAND Russian patent published in 2012 - IPC C07C209/10 C07C211/45 C07C211/61 B01J31/24 

FIELD: chemistry.

SUBSTANCE: invention refers to the improved method of production of formula I compounds, Where R₁ group is an A₁ group where groups R₂, R₃, R₄ and R₅ are each hydrogen. Said compounds are the intermediate products for fungicides synthesis. The method includes the process, where formula II compound Where groups R₁ and R₂ are defined as stated for formula 1, and X is the chlorine, interacts with ammonia in presence of the base and of catalytic amount of at least one complex palladium compound where a complex palladium compound includes at least one ferrocenylbiphosphinic ligand chosen out of R(-)-di-tert-buthyl[1-[(S)-2(dicyclohexylphosphinil)ferrocenyl]ethyl]-phosphine and racemic di-tert-buthyl[1-[2(dicyclohexylphosphinil)ferrocenyl]ethyl]-phosphine. The reaction is performed in inert solvent. The complex palladium compound is preferably used with the ratio from 1:10000 to 1:10 relative to formula II compound and formula II compound is used in concentration from 0.01M to 5M. Proposed method can be used for commercial production of intender product.

EFFECT: high output and good quality of the product with simplified technology.

4 cl, 2 tbl, 9 ex