METHOD FOR OBTAINING PROPIONIC ACID DERIVATIVES Russian patent published in 2016 - IPC C07D413/12 C07F9/28 B01J31/22 

Abstract RU 2575345 C2

FIELD: chemistry.

SUBSTANCE: claimed invention relates to method for obtaining compound of formula or its salt by hydration of formula compound or its salt in presence of catalyst, including iridium and compound of formula , where R1 represents alkyl, aryl or arylalkyl and R2 represents aryl. Catalyst represents Ir(L1)(L2)nY, where L1 represents compound of formula (X), L2 represents cyclooctane, 1,5-cyclooctadiene, ethylene, 1,5-hexadiene or norbornadiene, Y represents chloride, iodide, bromide, fluoride, trifluoroacetate, tetrafluoroborate, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, tetraphenylborate, hexafluoroantimonate, hexafluorophosphate, triflate, mesylate, perchlorate, perbromate, periodate, nitrate, hydrosulphate or acetylacetonate, and n has values 1 or 2.

EFFECT: obtaining compound of formula (I) with high enatiomeric excess and high output.

7 cl, 4 tbl, 35 ex

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RU 2 575 345 C2

Authors

Kurt Pjuntener

Mikelandzhelo Skalone

Dates

2016-02-20Published

2011-02-03Filed