FIELD: chemistry.
SUBSTANCE: claimed invention relates to method for obtaining compound of formula or its salt by hydration of formula compound or its salt in presence of catalyst, including iridium and compound of formula , where R1 represents alkyl, aryl or arylalkyl and R2 represents aryl. Catalyst represents Ir(L1)(L2)nY, where L1 represents compound of formula (X), L2 represents cyclooctane, 1,5-cyclooctadiene, ethylene, 1,5-hexadiene or norbornadiene, Y represents chloride, iodide, bromide, fluoride, trifluoroacetate, tetrafluoroborate, tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, tetraphenylborate, hexafluoroantimonate, hexafluorophosphate, triflate, mesylate, perchlorate, perbromate, periodate, nitrate, hydrosulphate or acetylacetonate, and n has values 1 or 2.
EFFECT: obtaining compound of formula (I) with high enatiomeric excess and high output.
7 cl, 4 tbl, 35 ex
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Authors
Dates
2016-02-20—Published
2011-02-03—Filed