FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing 2- and 4-(1,3,5-dithiazinan-5-yl)-phenols of general formula 
(1), which involves reaction of o- or n-aminophenol with N-methyl-1,3,5-dithiazinane in the presence of a samarium nitrate crystalline hydrate catalyst [Sm(NO3)2*6H2O], taken in molar ratio o-, or n-aminophenol: N-methyl-1,3,5-dithiazinane: Sm(NO3)2*6H2O = 10:(10-12):(0.3-0.7), in an atmosphere of argon in a medium of EtOH-CHCl3 as a solvent at temperature 50-70°C and atmospheric pressure for 2.5-3.5 hours.
EFFECT: method which enables to obtain a compound with high selectivity and low toxicity of the process.
1 cl, 1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING N-ARYL-1,3,5-DITHIAZINANES | 2010 |
|
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| METHOD FOR SYNTHESIS OF 2- AND 4-(1,3,5-DITHIAZINAN-5-YL)-PHENOLS | 2010 |
|
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|
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|
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| METHOD FOR PREPARING 3-(o-, m-, p-NITROPHENYL)-1,5,3-DITHIAZEPANES | 2011 |
|
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| METHOD FOR PREPARING 3-(m-, p-METHYLPHENYL)-1,5,3-DITHIAZEPANES | 2011 |
|
RU2478625C2 |
| METHOD OF OBTAINING 3-(o-,m-,p-METHOXYPHENYL)-1,5,3-DITHIAZEPANES | 2011 |
|
RU2466998C1 |
| METHOD OF OBTAINING 3,3'-(1,2-PHENYLENE)-BIS-1,5,3-DITHIAZEPINANE AND 3,3,-[METHYLENE-BIS-(1,4-PHENYLENE)]-BIS-1,5,3- DITHIAZEPINANE | 2011 |
|
RU2467006C1 |
| METHOD OF OBTAINING 4-(1,5,3-DITHIAZEPINAN-3-YL)-BENZOIC AND 5-(1,5,3-DITHIAZEPINAN-3-YL)-2-HYDROXYBENZOIC ACIDS | 2012 |
|
RU2529516C2 |
| METHOD OF SELECTIVE OBTAINING 3,3'-[METHYLENEBIS(1,4-PHENYLENE)]-, 3,3'-[OXYBIS(1,4-PHENYLENE)]- AND 3,3'-(3,3'-DIMETHOXYBIPHENYL-4, 4'-DIYL)-BIS-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2518485C2 |
