METHOD OF PRODUCING ISOPRENE Russian patent published in 2012 - IPC C07C11/18 C07C1/20 B01J21/02 B01J21/04 B01J21/08 B01J21/10 B01J23/06 B01J23/30 B01J23/14 B01J23/34 

Abstract RU 2448939 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing isoprene by reacting an organic C4 compound and methylal in vapour phase on a fixed catalyst bed which is boron phosphate containing at least one oxide and/or a compound which can be easily decomposed to oxides, selected from a group comprising aluminium, magnesium, zinc and silicon, characterised by that the organic C4 compound used is tertiary butyl alcohol, the process is carried out in an apparatus, having at least one section filled with a catalyst, and the catalyst used further contains at least one oxide and/or a compound which can be easily decomposed to oxides, selected from a group comprising manganese, tungsten, tin, titanium and zirconium, with the following content of components, wt %: oxides and/or compounds easily decomposed to oxides, selected from a group comprising aluminium, magnesium, zinc and silicon 1.5-65; oxides and/or compounds easily decomposed to oxides, selected from a group comprising manganese, tungsten, tin, titanium and zirconium 0.1-28; boron phosphate - the rest.

EFFECT: use of the present method widens the raw material base, increases selectivity and increases periods between catalyst regeneration.

8 cl, 7 ex, 1 tbl

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RU 2 448 939 C1

Authors

Kotel'Nikov Georgij Romanovich

Sidnev Vladimir Borisovich

Kachalov Dmitrij Vasil'Evich

Lugovkin Sergej Nikolaevich

Komarov Stanislav Mikhajlovich

Churkin Vladimir Nikolaevich

Glushakov Mikhail Ivanovich

Dates

2012-04-27Published

2011-01-11Filed