FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing olefin oxides. According to the invention, olefins undergo epoxidation with isopropylene benzene hydroperoxide at temperature 90-120°C in the presence of a molybdenum-containing catalyst obtained by dissolving molybdenum metal in isopropylene benzene hydroperoxide and ethyl alcohol in volume ratio 1:1, into which a Mannich base is added with molar ratio of molybdenum to Mannich base equal to (0.2-0.5).
EFFECT: simple method of producing olefin oxides through a process without solvents and high technological parameters of the epoxidation process.
1 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING OLEFIN OXIDES | 2011 |
|
RU2463297C1 |
METHOD FOR EPOXYDATION OF OLEFINS | 2004 |
|
RU2263671C1 |
METHOD FOR PRODUCING CATALYST FOR EPOXYDATION OF OLEFINS | 2018 |
|
RU2683319C1 |
METHOD OF PRODUCING MOLYBDENUM CATALYST FOR OLEFIN EPOXIDATION | 2016 |
|
RU2633363C1 |
OLEFIN EPOXIDATION CATALYST AND A METHOD FOR PREPARATION THEREOF | 2003 |
|
RU2240181C1 |
METHOD OF PRODUCING MOLYBDENUM-CONTAINING CATALYST FOR OLEFIN EPOXIDATION | 1993 |
|
RU2050977C1 |
METHOD OF PRODUCING MOLYBDENUM CATALYST FOR OLEFIN EPOXIDATION | 2014 |
|
RU2556002C1 |
METHOD OF PREPARING MOLYBDENUM-CONTAINING CATALYST FOR EPOXIDATION OF OLEFINS | 2004 |
|
RU2256500C1 |
METHOD OF RECOVERING MOLYBDENUM FORM CATALYTIC OLEFIN EPOXIDATION PRODUCTS | 2004 |
|
RU2268885C1 |
PROCESS FOR PREPARING ALPHA-OXIDES OF OLEFFINS | 0 |
|
SU1066995A1 |
Authors
Dates
2012-09-20—Published
2010-07-01—Filed