FIELD: organic chemistry, chemical technology.
SUBSTANCE: invention proposes method for epoxydation of olefins with ethyl benzene hydroperoxide in the presence of molybdenum-containing catalyst and nitrogen-containing compound. Derivatives of quinolines or Mannich base or their mixtures are used as nitrogen-containing compound and the mole ratio molybdenum : nitrogen-containing compound is maintained = 1:(0.05-0.4). Invention provides enhancing conversion and selectivity of the epoxydation process of olefins with organic hydroperoxides.
EFFECT: improved method for epoxydation.
3 cl, 15 ex
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Authors
Dates
2005-11-10—Published
2004-06-29—Filed