POLYMERS OF N-GLYCIDYL-3-NITRO-5-R-1,2,4-TRIAZOLES AND PRODUCTION METHOD THEREOF Russian patent published in 2012 - IPC C08F8/30 

FIELD: chemistry.

SUBSTANCE: disclosed are (co)polymers of N-glycidyl-3-nitro-5-R-1,2,4-triazoles of general formula I , where R₁=H, CH₂N₃, ; n=50-100 mol %; m=0-50 mol %. The invention also discloses versions of the method of producing the disclosed compounds: for producing a compound of formula I, where R₁=H or

- treatment of a sodium salt of 3-nitro-5-R-1,2,4-triazole or a sodium salt of 3-nitro-5-R-1,2,4-triazole 1.5-hydrate, where R=H, CH₃, C₂H₅ with (co)polymers of glycidyl chloride of general formula II , where R₂=H; CH₂Cl, with molar ratio (sodium salt of 3-nitro-5-R-1,2,4-triazole or sodium salt of 3-nitro-5-R-1,2,4-triazole 1.5-hydrate): ((co)polymer of glycidyl chloride) = 1.5:1.0, and for producing a compound of formula I, where R₁= CH₂N₃- treatment of sodium salt of 3-nitro-5-R-1,2,4-triazole or sodium salt of 3-nitro-5-R-1,2,4-triazole 1.5-hydrate, where R=H, CH₃, C₂H₅ and sodium azide with a glycidyl chloride polymer of general formula II with molar ratio (sodium salt of 3-nitro-5-R-1,2,4-triazole or sodium salt of 3-nitro-5-R-1,2,4-triazole 1.5-hydrate) : (sodium azide) : ((co)polymer of glycidyl chloride) = (1.0-1.25):(0.25-0.5):1.0. Treatment is carried out in dimethyl formamide medium at temperature 95-135°C for 3-10 hours.

EFFECT: disclosed polymers have high volume of products during combustion, high density and content of nitrogen and can be used as components of gas-generating compositions and organic synthesis reactants.

3 cl, 4 tbl, 13 ex