FIELD: chemistry.
SUBSTANCE: method involves reacting a polymer solution in an organic solvent with an epoxidation agent. The epoxidation agent used is aqueous sodium hypochlorite solution with concentration of 0.05-0.2 mol/l. The reaction is carried out in molar ratio 1,2-polybutadiene:sodium hypochlorite = 1.0:0.2-1.0, at temperature 20-30°C for 2-5 hours at reaction medium pH of 10.5-11.5.
EFFECT: method of producing epoxidated 1,2-polybutadienes, characterised by high safety of the process, low power consumption and high quality of the end product.
3 cl, 1 tbl, 14 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING EPOXIDATED 1,2-POLYBUTADIENES | 2011 |
|
RU2456301C1 |
| METHOD OF PRODUCING EPOXIDATED 1,2-POLYBUTADIENES | 2012 |
|
RU2486210C1 |
| METHOD OF PRODUCING EPOXIDATED 1,2-POLYBUTADIENES | 2012 |
|
RU2486207C1 |
| METHOD OF PRODUCING EPOXIDATED 1,2-POLYBUTADIENES | 2012 |
|
RU2509781C1 |
| METHOD FOR SURFACE MODIFICATION OF 1,2-POLYBUTADIENES WITH EPOXY GROUPS | 2012 |
|
RU2488599C1 |
| METHOD OF PRODUCING EPOXIDATED 1,2-POLYBUTADIENES | 2012 |
|
RU2509780C1 |
| METHOD OF PRODUCING CHLORINATED 1,2-POLYBUTADIENES | 2011 |
|
RU2462478C1 |
| METHOD OF OBTAINING PHOSPHORYLATED 1,2-POLYBUTADIENES | 2013 |
|
RU2535374C1 |
| METHOD OF OBTAINING BORATED 1,2-POLYBUTADIENES | 2013 |
|
RU2535679C1 |
| METHOD OF PRODUCING HYDROGENATED 1,2-POLYBUTADIENE DERIVATIVES | 2013 |
|
RU2538955C1 |
