HIGH-MOLECULAR WEIGHT POLYMER ESTERS CHARACTERISED BY LOW CONTENT OF ACETALDEHYDE Russian patent published in 2013 - IPC C08G63/00 C08G63/02 C08G63/181 C08G63/183 C08G63/85 

Abstract RU 2474592 C2

FIELD: chemistry.

SUBSTANCE: method of obtaining solid particles involves the following steps: polycondensation of a composition of said polyester in the presence of a catalyst containing at least 5 ppm titanium compounds; adding a catalyst deactivator; curing the composition after achieving characteristic viscosity of 0.69 dl/g until solid particles are obtained, wherein the obtained particles do not contain added aldehyde acceptors; reducing the amount of residual acetaldehyde in the particles to 10 ppm or less without increasing the value of characteristic viscosity by more than 0.03 dl/g. Said catalyst deactivator is added in different conditions which are described in the claim. The method of making articles involves feeding into a processing zone solid particles in a melt and an additional catalyst deactivator containing a phosphorus compound in an amount which satisfies the ratio P:Ti which is less than 2.5:1; melting the particles and making articles.

EFFECT: obtaining solid polyester particles which are used for food containers and beverages without using a solid phase polymerisation technique, and are characterised by low content of acetaldehyde in the absence of organic acetaldehyde acceptors.

21 cl, 12 tbl

Similar patents RU2474592C2

Title Year Author Number
POLYESTER POLYMERS WITH LOW RATE OF FORMATION OF ACETALDEHYDE AND HIGH CONCENTRATION OF TERMINAL VINYL GROUPS 2008
  • Dzhernigan Mehri Tereza
RU2458074C2
ALUMINIUM-CONTAINING POLYESTER POLYMERS, HAVING LOW RATE OF FORMATION OF ACETALDEHYDE 2006
  • Dzhernigan Mehri Tereza
  • Armentraut Rodni Skott
  • Venett Kenrik Lajl
  • Debruin Brjus Rodzher
RU2448124C2
POLYESTERS CONTAINING ALUMINIUM/ALKALI METAL OR ALKALI/TITANIUM, HAVING HIGH REHEATING CAPACITY, IMPROVED COLOUR AND TRANSPARENCY 2006
  • Kvillen Donna Rajs
  • Armentraut Rodni Skott
  • Dzhernigan Mehri Tereza
  • Stehfford Stiven Li
  • Sja Chzhijun
RU2434900C2
PROCEDURE FOR INTRODUCTION OF ADDITIVES INTO POLYMER MELT 2006
  • Debruin Brjus Rodzher
  • Vennett Kenrik Lajl
RU2418010C2
POLYMERS BASED ON POLYESTERS HAVING HIGH INTRINSIC VISCOSITY OF MOLTEN PHASE WITH SUITABLE RATE OF FORMATION OF ACETALDEHYDE 2006
  • Dzhernigan Mehri Terez
RU2402575C2
POLYMER MATERIALS 2014
  • Brennon Filip
RU2664935C2
REMOVAL OF RESIDUAL ACETALDEHYDE FROM POLYESTER PARTICLES 2005
  • Armentraut Rodni Skott
  • Kolkhaun Frederik Lesli
  • Ehkart Majkl Pol
  • Debruin Brjus Rodzher
RU2388767C2
POLYESTER COMPOSITIONS WITH IMPROVED THERMAL-OXIDATIVE STABILITY OBTAINED IN MELT, AND METHOD OF THEIR OBTAINING AND APPLICATION 2009
  • Dzhenkins Dzhejson Kristofer
  • Briki Dennis Ehdvard
  • Khauehll Ehrl Ehdmondson Ml.
  • Grin Kehrol Dzhulliard
RU2516848C2
SPHEROIDAL PARTICLES OF POLYESTER POLYMERS 2005
  • Uehjnkhold Stefen
  • Kolkhaun Frederik Lesli
  • Ehkart Majkl Pol
  • Gehmbl Bendzhamin Brehdford
RU2386645C2
MOLTEN PHASE-DERIVED POLYESTER-BASED COMPOSITIONS HAVING IMPROVED THERMAL OXIDATIVE STABILITY, AND METHODS OF PRODUCING AND USING SAID COMPOSITIONS 2009
  • Dzhenkins Dzhejson Kristofer
  • Briki Denis Ehdvard
  • Khauehll Ehrl Ehdmondson
  • Grin Kehrol Dzhulliard
RU2550211C2

RU 2 474 592 C2

Authors

Dzhernigan Mehri Tereza

Dates

2013-02-10Published

2008-05-14Filed