FIELD: oil and gas industry.
SUBSTANCE: invention refers to petrochemistry, and namely to the process of deep desulphurisation of diesel hydrocarbon fuels. The invention refers to the method of deep oxidation-absorption desulphurisation of liquid hydrocarbon fuels, which involves preparation of a loose sorbent by mixing high-porous absorbents with nitric-acid salt of metal and further treatment of liquid hydrocarbons with the above sorbent, in which the sorbent can contain the binding agent as well, at that, the high-porous absorbent has been chosen from the group of bentonite, montmorillonite, absorbent carbon or high-porous silicon, and nitric-acid salt of metal has been chosen from the group of ferric nitrate, nickel nitrate, copper nitrate; prior to the treatment of liquid hydrocarbons, mixture of the sorbent ingredients is granulated to the particle sizes of 1-5 mm with specific sorbent surface of 50-600 m2/g; at that, treatment is performed by passing the flow of liquid hydrocarbons through a layer of granulated sorbent with volumetric velocity of not more than 100 h-1. The invention also refers to compositions of sorbents used for the method's realisation.
EFFECT: increasing the efficiency of liquid hydrocarbon fuel cleaning from sulphur containing compounds and providing the continuous process.
5 cl, 1 dwg, 1 tbl, 8 ex
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Authors
Dates
2013-05-20—Published
2012-02-01—Filed