FIELD: metallurgy.
SUBSTANCE: solid extractant is proposed (SEX) for extraction of scandium from scandium-containing solutions, containing a styrene divinyl benzene matrix with di-(2-ethyl hexyl)phosphoric acid. At the same time it additionally contains dibenzo-18-crown-6 at the following ratio of components, wt %: di-(2-ethyl hexyl)phosphoric acid 28-30, dibenzo-18-crown-6 28-30, styrene divinyl benzene - balance, besides, the ratio of styrene and divinyl benzene in the matrix is equal to 65÷70:30÷35. There is a method also suggested for production of the above extractant.
EFFECT: quite high selectivity by scandium and efficient separation of scandium and yttrium with their joint existence in a solution.
2 cl, 2 ex
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Authors
Dates
2013-07-10—Published
2011-11-03—Filed