FIELD: chemistry.
SUBSTANCE: invention relates to a catalyst system for hydrotreatment of heavy oils. Said catalyst system includes a catalyst having a hydrogenation catalyst function and a cocatalyst. Said catalyst having a hydrogenation function is selected from: a catalyst consisting of MoS2 or WS2, or a mixture thereof in form of plates, or an oil-soluble precursor thereof; a catalyst consisting of MoS2 or WS2, or a mixture thereof in form of plates, or an oil-soluble precursor thereof and V, Ni and Fe sulphides; a catalyst consisting of MoS2 distributed in a carbon-containing matrix which includes crystalline domains of V, Ni and Fe sulphides. The cocatalyst includes nano- or microparticles and is selected from cracking and/or denitrification catalysts, where said cocatalyst consists of zeolites and/or supported oxides, or sulphides, or Ni and/or Co sulphide precursors, in a mixture with Mo and/or W. The invention also relates to a method for hydrotreatment of heavy oils using said catalyst system.
EFFECT: disclosed catalyst system has a synergetic effect on the reaction medium.
13 cl, 2 tbl, 5 ex
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Authors
Dates
2014-08-20—Published
2009-06-08—Filed