FIELD: electricity.
SUBSTANCE: at the stage of realisation of the method on a conducting substrate by the method of magnetron dispersion of a vanadium target in plasma of oxygen and argon at the oxygen/argon ratio 0.01-0.06 by partial pressure, without forced heating of the metal substrate, they produce a textured film, having within its composition vanadium oxides VO1+x, V3O7, V2O5 at different ratio, and at the second stage they expose it to subsequent baking in the oxygen-containing medium at 400-500°C for 10-120 min, to produce high vanadium oxides V6O13, V3O7, VO2, V2O5 in the film in polycrystalline phase. A lithium-ion accumulator includes a thin-film positive electrode on the basis of films of vanadium oxides, having a crystalline structure, produced by the proposed method, a negative electrode, electrolyte and separator.
EFFECT: increased electric specific capacity.
2 cl, 8 dwg, 3 ex
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Authors
Dates
2014-08-20—Published
2013-03-26—Filed