AMMOXIMATION METHOD Russian patent published in 2014 - IPC C07C249/04 C07C249/08 B01J29/84 C07C251/44 C01B37/06 C07D223/10 

FIELD: chemistry.

SUBSTANCE: invention relates to a redox ammoximation method, wherein a ketone or aldehyde reacts with ammonia and oxygen in the presence of a catalyst, where the catalyst is a redox catalyst based on aluminophosphate, having a qualitative general formula M¹M²AlPO-5 (I), where M¹ denotes at least one transition metal selected from Co(III), Mn(III), Fe(III), Cr(VI), Cu(III), V(V) and Ru(III); M² denotes a metal selected from Ge(IV), Sn(IV), Re(IV), V(IV) and mixtures thereof; M¹ and M² are different from each other; and a certain portion of phosphorus atoms in the structure of the type M¹M²AlPO-5 is substituted with atoms of M². Also disclosed is a redox ammoximation catalyst.

EFFECT: providing a selective ammoximation method.

11 cl, 5 tbl, 6 dwg, 16 ex