FIELD: chemistry.
SUBSTANCE: invention relates to optic materials, in particular to melt alumoborate glass, activated by trivalent ions of cerium (Ce3+) and terbium (Tb3+), which can be used as a visualiser of ultraviolet images and light transformer from ultraviolet into the yellow-green area of the spectrum. Glass (versions) has the following composition, mol.%:B2O3 55-70, Al2O3 15-35, La2O3 1-10, Ce2O3 1-5, Tb2O3 2-10 and over 100% Sb2O3 0.5-5 or B2O3 55-70, Al2O3 15-35, Y2O3 1-9, La2O3 1-9, Ce2O3 1-5, Tb2O3 2-1 and over 100% Sb2O3 0.5-5 or B2O3 55-70, Al2O3 15-35, Y2O3 1-9, La2O3 1-9, Ce2O3 1-5, Gd2O3 1-9, Tb2O3 2-10 and over 100% Sb2O3 0.5-5, or B2O3 55-70, Al2O3 15-35, Y2O3 1-10, Ce2O3 1-5, Tb2O3 2-10 and over 100% Sb2O3 0.5-5, or B2O3 55-70, Al2O3 15-35, Gd2O3 1-10, Ce2O3 1-5, Tb2O3 2-10 and over 100% Sb2O3 0.5-5, with the atomic ratio Tb/Ce≥1.
EFFECT: creation of glass with high active absorption in the ultraviolet area of the spectrum and efficient luminescence in the area of the maximal spectral sensitivity of the human eye.
5 cl, 1 dwg, 1 tbl
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Authors
Dates
2014-11-27—Published
2012-10-26—Filed