FIELD: chemistry.
SUBSTANCE: invention relates to a method of cleaning motor fuel, which includes extraction of sulphur-containing compounds from fuel into an ionic liquid, partial oxidation of the extracted sulphur-containing compounds under the action of a catalyst in an alcohol-alkaline solution or in an acidic aqueous solution, separation of the hydrocarbon fraction and reclamation of the ionic liquid. The ionic liquid used consists of: a cation selected from a group comprising alkylimidazolium, alkylpyridinium, polyalkylammonium, alkylpiperidinium, and an anion selected from a group comprising tetrafluoroborate, hexafluorophosphate, trifluoromethylsulphonate (triflate), bis(trifluoromethylsulphonyl)imide, nitrate, acetate, chloride, hydrosulphate. The ionic liquid is taken in volume ratio of 1:10-1:5 to the fuel to be cleaned. The catalyst is used in a solution containing at least one metal and/or metal oxide in a higher oxidation state with concentration of 1.0-40 mmol/l. The metal is selected from a group of transition metals which includes molybdenum, vanadium, tungsten, manganese and chromium. Mechanical agitation is carried out in a closed vessel at a temperature not higher than the boiling point of the fuel.
EFFECT: high degree of purity motor fuel.
18 cl, 2 tbl, 12 ex
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Authors
Dates
2015-02-10—Published
2013-10-18—Filed