FIELD: chemistry.
SUBSTANCE: boron-based material having a deformation stability of ΔL/L0=3.0÷7.5% at 600°C is produced by conducting a reaction of sodium silicate Na2O(SiO2)n in an aqueous solution of caustic soda with trimethylammonium decahydroclosodecaborate (Me3NH)2B10H10. The reaction solution is boiled until trimethylamine formed by the reaction of caustic soda and (Me3NH)2B10H10 is removed completely, then dried with increasing the temperature to 300°C; that makes prepare the material described by chemical formula: [Na2O(SiO2)n]m[Na2B10H10]k, wherein: n is an initial sodium silicate characteristics via a silicate module, which varies within the range of 2.5÷3.0; m:k=7.0÷1.9; a decahydroclosodecaborate anion binds to sodium atoms both of sodium silicate, and sodium silicate by multicentre reactions resultant in forming spatial supramolecular structures.
EFFECT: producing the neutron-protective material with no high energy costs and additional equipment.
1 tbl
Title | Year | Author | Number |
---|---|---|---|
POLYHEDRAL CLOSO-HYDROBORATES OF CHITOSAN AND METHOD OF PREPARATION THEREOF | 1998 |
|
RU2158221C2 |
KLOZO-BORATE CLUSTER PRODUCTION METHOD | 2007 |
|
RU2344070C1 |
BORON-FLUORIDE-CONTAINING ENERGY-INTENSIVE COMPOSITION FOR ENERGY CONDENSED SYSTEMS AND METHOD OF ITS PRODUCTION | 2017 |
|
RU2640338C1 |
ENERGY-RICH COMPOSITION CONTAINING BORON AND FLUORINE AND METHOD OF ITS PRODUCTION | 2015 |
|
RU2610605C1 |
AMINO-ACID DERIVATIVE OF THE DECAHYDRO-CLOSO-DECABORATE ANION AND ITS ANTIVIRAL ACTIVITY AGAINST INFLUENZA A VIRUS | 2020 |
|
RU2749006C1 |
SILICON DIOXIDE-BASE SOLS | 2000 |
|
RU2213053C2 |
METHOD FOR OBTAINING POTASSIUM DODECAHYDRO-CLOSO-DODECABORATE | 2013 |
|
RU2573679C2 |
METHOD OF PRODUCING BLOCKED FOAMED GLASS | 2015 |
|
RU2594416C1 |
CATALYST FOR CONVERSION OF HYDROCARBONS | 1989 |
|
RU2067024C1 |
2,4-DIAMINE-6-PHENYL-1,3,5-TRIAZINE DODECAHYDRO-CLOSO-DODECABORATE HYDRATE, METHOD OF ITS PREPARATION AND USE AS PRECIPITATING FORM OF BH ANION | 2023 |
|
RU2810492C1 |
Authors
Dates
2015-05-10—Published
2014-06-03—Filed