FIELD: chemistry.
SUBSTANCE: method of purification of phenol-containing sewage waters of alkali-hydrolysis processing of rice husk includes preliminary desiliconisation of phenol-containing sewage waters by their processing with hydrochloric acid with precipitation of solid and separation from solution of silicon-containing product and electrochemical oxidation in presence of chloride ions in electrolytic cell with application of direct current. Process of electrochemical oxidation is carried out with concentration of chloride ions 0.10-0.11 mol/l in non-diaphragm electrolytic cell with application of ruthenium-titanium oxide anode and titanium cathode for 70-90 min with current density 100-150 mA/cm2 with constant mixing. Required concentration of chloride ions is provided by dilution with water of phenol-containing sewage waters after their desiliconisation.
EFFECT: invention makes it possible to increase degree of purification of polydisperse concentrated phenol-containing sewage waters of alkali-hydrolysis processing of rice husk from phenol and other organic pollutants.
3 cl, 1 tbl, 2 ex
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Authors
Dates
2015-07-10—Published
2014-05-28—Filed