INSTALLATION FOR OBTAINING ALDEHYDES BY HYDROFORMYLATION OF C3-C4 OLEFINS WITH APPLICATION OF CATALYTIC RHODIUM-BASED SYSTEM Russian patent published in 2015 - IPC B01J19/24 C07C45/50 C07C47/02 

Abstract RU 2559052 C1

FIELD: chemistry.

SUBSTANCE: installation includes: connected to reactor in parallel way via purification devices sources of synthesis-gas and olefin, successively connected via pipelines with product output from reactor gas-liquid high-pressure separator, device for separation of product aldehydes from catalyst solution, connected with reactor by pipeline of catalyst solution recycle, collector of product aldehyde, rectification column, connected with pipeline of catalyst solution recycle unit of waste catalyst collection and unit of feeding fresh catalyst, as well as line of gas recycle. Installation is provided with gas-liquid separator of low pressure with regulator of gas pressure and stripper, successively installed between gas-liquid high-pressure separator and device for separation of product aldehydes from rhodium-containing catalyst solution, made in form if film evaporator, installed on output of exhaust gases from collector of product aldehyde compressor, refrigerator-condenser and additional high-pressure separator, with output for gas from main high-pressure separator being connected with stripper, output for gas in which is connected with line of gas recycle, with outputs for gases of low-pressure separator and additional high-pressure separator being connected with film evaporator, input of which and stripper are connected with source of synthesis-gas.

EFFECT: realisation of hydroformylation on claimed installation makes it possible to increase degree of extraction and re-use of raw material, which does not react during one passage through reactor, increase total conversion of olefins, reduce thermal destruction of catalyst and loss of product aldehydes in the process of separating the latter from catalyst solution, as well as reduce loss of catalyst in the process of catalyst solution recycle.

1 dwg, 1 ex

Similar patents RU2559052C1

Title Year Author Number
METHOD FOR CONTINUOUS TWO-STEP HYDROFORMYLATION OF C3, C4 OLEFINS AND PROCESS APPARATUS THEREFOR 2014
  • Noskov Jurij Gennad'Evich
  • Rush Sergej Nikolaevich
  • Kostin Andrej Mikhajlovich
  • Korneeva Galina Aleksandrovna
RU2561171C1
TECHNOLOGICAL INSTALLATION FOR OBTAINING ALDEHYDES, MAINLY FROM BUTANES OR PROPYLENE, WITH APPLICATION OF RHODIUM CATALYSTS 2014
  • Noskov Jurij Gennad'Evich
  • Rush Sergej Nikolaevich
  • Kostin Andrej Mikhajlovich
  • Korneeva Galina Aleksandrovna
RU2557062C1
METHOD FOR CONTINUOUS HYDROFORMYLATION OF OLEFINS C-C 2015
  • Korolev Yurij Aleksandrovich
  • Noskov Yurij Gennadevich
  • Kron Tatyana Evgenevna
  • Rush Sergej Nikolaevich
  • Kostin Andrej Mikhajlovich
  • Korneeva Galina Aleksandrovna
RU2585285C1
PROPIONATES, N-PROPANOL AND PROPIONIC ACID PRODUCTION PLANT 2023
  • Sulimov Aleksandr Vladimirovich
  • Fedotov Konstantin Vladimirovich
  • Sidelnikova Ekaterina Andreevna
  • Norin Vladislav Vadimovich
RU2815838C1
METHOD OF ALDEHYDES C-CPRODUCTION 2007
  • Noskov Jurij Gennad'Evich
  • Rush Sergej Nikolaevich
  • Kron Tat'Jana Evgen'Evna
  • Kulik Aleksandr Viktorovich
  • Korneeva Galina Aleksandrovna
RU2354642C2
METHOD OF PRODUCING BUTYL ALDEHYDES IN PRESENCE OF UNMODIFIED COBALT CATALYST 2008
  • Sokolov Boris Gennad'Evich
  • Borisov Rim Borisovich
  • Gil'Chenok Naum Davydovich
  • Petrov Anatolij Nikolaevich
  • Sokolov Maksim Borisovich
RU2393145C1
METHODS FOR CONVERTING OLEFINS INTO ALCOHOLS, ESTERS, OR COMBINATIONS THEREOF 2017
  • Beker Majkl K.
  • Brammer Majkl A.
  • Dzhajlz Dzhejson F.
  • Miller Glenn A.
  • Fillips Dzhordzh R.
  • Vatson Rik B.
  • Vamberg Stefani
  • Smidt Martin Lukas
RU2751511C2
METHOD OF HEAT REGULATION INCLUDING THE COOLED GAS EXPANSION BY COOLING AND RE-CIRCULATION 2014
  • Miller, Glenn, A.
  • Koks, Irvin, B.
  • Mokhtarzadekh, Morteza
RU2664800C2
METHOD FOR PREPARING ALDEHYDES COMPRISING 3-21 CARBON ATOMS 2001
  • Vize Klaus-Diter
  • Trokha Martin
  • Rettger Dirk
  • Tech Val'Ter
  • Kajtsik Al'Fred
  • Bjushken Vil'Frid
RU2270829C2
HYDROFORMYLATION METHOD 2017
  • Simpson Ketlin
  • Smit Dzherald L.
RU2724349C2

RU 2 559 052 C1

Authors

Noskov Jurij Gennad'Evich

Rush Sergej Nikolaevich

Kostin Andrej Mikhajlovich

Korneeva Galina Aleksandrovna

Dates

2015-08-10Published

2014-06-26Filed