METAL-FREE BLEACHING COMPOSITION Russian patent published in 2015 - IPC C07C225/10 C11D3/30 C11D3/39 C11D3/395 D06L3/02 

Abstract RU 2570902 C2

FIELD: chemistry.

SUBSTANCE: invention relates to use of a composition containing H2O2, a H2O2 precursor or a peroxy acid, and a compound of formula for bleaching stains or dirt on textile materials during a cleaning process or by direct application of a stain remover at pH of 7 to 11. In formulae (1) and (2) X- is an anion of an organic or inorganic acid selected from BF4-, PF6-, RSO3-, RSO4-, SO42-, or Cl-, where R is C1-C24 alkyl; R1 is hydrogen, phenyl-(SO)-, a straight C1-C6-alkyl, C1-C6-alkoxy group, C1-C6-alkylthio group, C1-C6-alkyl-S(O)-, C1-C6-alkyl-SO2-, where the C1-C6-alkyl is unsubstituted or substituted with (CO)OR6; or R1 is S+(R7)(R8)X'-; R7 and R8 independently denote a straight C1-C6-alkyl; X'- has one of the values defined for X-, and is the same or different; or R1 is N+(R9)(R10)(R11)X"-; R9, R10 and R11 independently denote a straight C1-C6-alkyl; X"- has one of the values defined for X- and X'-, and is the same or different; R'1 has one of the values defined for R1; R2 and R3 independently denote hydrogen or a straight C1-C6-alkyl; or R2 and R3 together with the atom with which they are bonded form a cyclopentyl or cyclohexyl group; R4 and R5 independently denote hydrogen, a straight or branched C1-C12-alkyl or C1-C6-alkyl, which is divided by one O atom; or R4 and R5 together with a nitrogen atom with which they are bonded form a pyrrolidine, piperidine or morpholine group or hexamethylene imine; R6 is hydrogen or a straight or branched C1-C3-alkyl, under the condition that if in formulae (1) and (2) R1, R'1, R2 and R3 denote hydrogen, then R4 and R5 do not denote an unsubstituted C1-C12-alkyl.

EFFECT: improved bleaching procedure, effective bleaching at high pH values without harmful effect on fibres and textile materials.

9 cl, 11 tbl

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RU 2 570 902 C2

Authors

Fraj Markus

Rover Khauke

Vendeborn Frederik

Khatsenkamp Menno

Dates

2015-12-20Published

2011-06-21Filed