FIELD: chemistry.
SUBSTANCE: accelerator solution contains (i) at least one organic solvent, (ii) a manganese salt, a copper salt or a combination thereof, and (iii) a complex of iron with a nitrogen donor ligand having a structure of the formula , where R is hydrogen, F, Cl, Br, hydroxyl, C1-4-alkyl-O-, -NH-CO-H, -NH-CO-C1-12-alkyl, -NH2, NH-C1-12-alkyl and C1-12-alkyl; R1 and R2 are C1-24-alkyl, C6-10-aryl and a group containing a heteroatom, capable of coordinating at a transition metal; R3 and R4 are hydrogen, C1-12-alkyl, C1-12-alkyl-O-C1-12-alkyl, C1-12-alkyl-O-C6-10-aryl, C6-10-aryl, C1-12-hydroxyalkyl and (CH2)nC(O)OR5, R5 is hydrogen and C1-4-alkyl, and n varies from 0 to 4, X is C=O, -[C(R6)2]y-, where y varies from 0 to 3, and each R6 is hydrogen, hydroxyl, C1-12-alkoxy and C1-12-alkyl.
EFFECT: invention enables to obtain a nontoxic accelerator, having high reactivity and high curing efficiency of the curable resin.
12 cl, 2 tbl, 6 ex
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Authors
Dates
2016-01-20—Published
2011-06-14—Filed