FIELD: chemistry.
SUBSTANCE: invention relates to component of catalyst, intended for olefin polymerisation, containing magnesium, titanium, halogen and donor of electrons, wherein donor of electrons is represented by at least one of succinates, described by formula
,
and in said cussinates, described by formula (I), content of succinate, described by Fischer projection formula, represented by formula
,
is higher or equal to 76.1 wt % and lower than 100 wt%. In formula (I) and in formula (II) R1 and R2, which can be similar or different from each other, can stand for possessing linear chain (C1~C20)-alkyl group, possessing branched chain (C3~C20)-alkyl or cycloalkyl group, (C6~C20)-aryl or (C7~C20)-alkylaryl or -arylalkyl group; R3 and R4, which can be similar or different from each other, stand for halogen atom, possessing linear chain (C1~C10)-alkyl, possessing branched chain (C3~C10)-alkyl, (C3~C10)-cycloalkyl, (C6~C10)-aryl or (C7~C10)-alkylaryl or -arylalkyl group, and R3 and R4 can be optionally bound with each other with formation of ring, and R1, R2, R3 and R4 can optionally contain heteroatoms.
EFFECT: obtaining catalyst with higher activity and stereospecificity.
23 cl, 1 tbl
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Authors
Dates
2016-04-10—Published
2011-08-12—Filed