FIELD: chemistry.
SUBSTANCE: invention relates to methods of producing polyglycerol thickeners. Described is a method of producing polyglycerol composition involving reaction of one or more glycerine monomers with polymerisation initiator which is a glucoside diester of formula: , where Z is a nodal structure, such as methylglucose derivative; each Nu represents polynucleophilic group containing -OH; each Hphob represents a hydrophobic group, such as oleate; each L′ is a primary binding group, such as -O-; h take on values from 1 to 12; b take on values from 1 to 11; h + b is equal to at least 4, and h/h+b is more than 0.35. Also described is a method of producing polyglycerol composition, involving reaction of two or more glycerine monomers representing glycerolcarbonate monomer and acetylated glycerolcarbonate monomer with polymerisation initiator, which is a glucoside diester or sorbitan diester of formula: , where Z is an nodal structure, which is methylglucose derivative or sorbitan derivative; each Nu is a nucleophilic group containing -OH; each Hphob represents a hydrophobic functional group, such as oleate; each L′ is a primary binding group, such as -O-; h take on values from 1 to 12; b take on values from 1 to 11; h+b is equal to at least 4, and h/h+b is more than 0.35.
EFFECT: obtaining polyglycerol composition.
15 cl, 4 dwg, 11 tbl, 5 ex
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Authors
Dates
2016-07-20—Published
2011-11-14—Filed