FIELD: chemistry.
SUBSTANCE: invention relates to catalysts (versions) for producing acetaldehyde in isomerisation of ethylene oxide, as well as to a method of preparing said catalysts. Active component of catalyst comprises zeolite of structure: MTT, TON, having composition: x Al2O3 - y El2O - SiO2, where x=0.1-5·10-2; y=2·10-3, El is at least one of elements of group 1 of periodic table, a compound which is used for hydrothermal synthesis of zeolite, or zeolite of same composition and structure subjected to thermo-steam treatment, selected from following: MFI, MEL, BEA, FER, MOR, FAU. Invention also relates to a method of producing acetaldehyde in isomerisation of ethylene oxide by passing steam-gas mixture of ethylene oxide with gas diluent, which can be nitrogen and/or any inert gas, and/or carbon dioxide, and/or air, and/or water vapour, through a layer of catalyst in presence of disclosed catalysts (versions).
EFFECT: technical result is increasing conversion of ethylene oxide and selectivity on acetaldehyde, which provides high output of acetaldehyde.
9 cl, 1 tbl, 36 ex
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Authors
Dates
2016-10-20—Published
2015-09-02—Filed