METHOD FOR PRODUCTION OF PYRIDINE AND METHYLPYRIDINES Russian patent published in 2016 - IPC C07D213/09 

Abstract RU 2599573 C2

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing pyridine and methylpyridines, which are widely used in production of medicinal agents, herbicides, corrosion inhibitors, rubber vulcanisation accelerators, etc. Method involves reaction of ethanol, formaldehyde and ammonia in presence of mesoporous aluminium silicates at 200-400 °C and volume rate of supply of raw material (w) equal to 2-7 h-1, molar ratio of ethanol: formaldehyde: ammonia is 1.0:0.4-1.2:1.5-5.0.

EFFECT: using present method enables to obtain pyridines at lower temperature with high output and low content of reaction products of "heavy" compounds, which are reason for coke formation and fast catalyst deactivation.

1 cl, 4 dwg, 3 tbl, 10 ex

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RU 2 599 573 C2

Authors

Dzhemilev Usein Memetovich

Kutepov Boris Ivanovich

Grigoreva Nellya Gennadievna

Filippova Nadezhda Aleksandrovna

Agliullin Marat Radikovich

Dates

2016-10-10Published

2015-02-25Filed