FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing pyridine and methylpyridines, which are widely used in production of medicinal agents, herbicides, corrosion inhibitors, rubber vulcanisation accelerators, etc. Method involves reaction of ethanol, formaldehyde and ammonia in presence of mesoporous aluminium silicates at 200-400 °C and volume rate of supply of raw material (w) equal to 2-7 h-1, molar ratio of ethanol: formaldehyde: ammonia is 1.0:0.4-1.2:1.5-5.0.
EFFECT: using present method enables to obtain pyridines at lower temperature with high output and low content of reaction products of "heavy" compounds, which are reason for coke formation and fast catalyst deactivation.
1 cl, 4 dwg, 3 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING PYRIDINE AND METHYLPYRIDINES | 2013 |
|
RU2555843C1 |
METHOD OF OBTAINING PYRIDINE AND METHYLPYRIDINES | 2013 |
|
RU2555844C1 |
PYRIDINES PRODUCTION METHOD | 2017 |
|
RU2688224C1 |
PYRIDINES PRODUCTION METHOD | 2017 |
|
RU2688162C1 |
PYRIDINES PRODUCTION METHOD | 2017 |
|
RU2688680C1 |
METHOD OF PRODUCING 3,5-DIMETHYLPYRIDINE | 2014 |
|
RU2608734C2 |
METHOD FOR SYNTHESISING 2,4,6-TRIMETHYLPYRIDINE OVER A HIERARCHICAL ZEOLITE CATALYST H-YMMM | 2020 |
|
RU2759567C1 |
ISOPENTENE OLIGOMERIZATION PROCESS | 2022 |
|
RU2794999C1 |
PENTENE OLIGOMERIZATION PROCESS | 2022 |
|
RU2794612C1 |
METHOD FOR PRODUCING 2,4,6-TRIMETHYLPYRIDINE IN PRESENCE OF HIERARCHICAL ZEOLITE CATALYST H-YMMM | 2020 |
|
RU2767452C2 |
Authors
Dates
2016-10-10—Published
2015-02-25—Filed