METHOD OF OIL SLUDGE PREPARATION FOR HYDROGENATION PROCESSING (VERSIONS) AND METHOD OF HYDROGENATION PROCESSING OF OIL SLUDGE THEREWITH (VERSIONS) Russian patent published in 2017 - IPC C10G45/08 B09B3/00 

FIELD: oil and gas industry.

SUBSTANCE: group of inventions relates to the processing of oil waste, namely oil sludge, into oil and may be used for disposal of oil sludge and production of distillate fractions with a temperature no higher than 520°C. According to the first option of the method the oil slurdge containing more that 5% by weight of mineral impurities is brought into contact with the solvent in the extractor for the hydrogenation processing. The extractor pre-purging is carried out with inert gas till the air is removed and the extraction is made with constant stirring and purging with the inert gas. Water, a solvent part and a light hydrocarbons fraction boiling up to 350°C are recovered from the extract. The remainder of the extract is separated for a liquid organic phase and a precipitate via settling and decantation. The latter is sent for re-extraction. The second extract is hot filtered at the excessive pressure of 0.4-0.6 MPa and a temperature of 45-50°C and the filtrate is mixed with a liquid organic phase to get the processed raw material. If oil sludge contains less than 5% by weight. of mineral impurities, then no sedimentation and decantation is made for its preparation immediately directing part of the extract devoid of light hydrocarbons to hot filtration. The solvent is removed from the filtrate or its mixture with the liquid organic phase by distillation, and from precipitate filtration - by evaporation, and return it to the cycle. The raw materials prepared for the hydrogenation processing under the first or second method are transfered into the reactor and the hydrogenator processing of the said raw materials in the presence of hydrogen and a catalyst MoS2 synthesized in situ from water solution of ammonium paramolybdate dispersed in the processed raw materials is carried out.

EFFECT: invention increases the degree of recycling of oil sludge preventing equipment corrosion and poisoning of the catalyst by mineral impurities contained in the oil sludge, and increasing distillate fractional yield during hydrogenation refining of oil sludge.

4 cl, 7 tbl, 10 ex