FIELD: chemistry.
SUBSTANCE: invention relates to a regenerated diesel fuel hydrotreating catalyst that has a pore volume of 0.3-0.8 ml/g, a specific surface area of 150-280 m2/g, an average pore diameter of 6-15 nm, including molybdenum, cobalt, sulfur and a carrier in its composition. In this case, molybdenum and cobalt are contained in the catalyst in the form of a mixture of complex compounds Co(C6H6O7), H4[Mo4(C6H5O7)2O11], H3[Co(OH)6Mo6O18], sulfur is contained in the form of sulfate anion SO42-, in the following concentrations, wt %: Co(C6H6O7) - 5,1-18,0; H4[Mo4(C6H5O7)2O11] - 7,5-15,0; H3[Co(OH)6Mo6O18] - 4,3-19,0; SO42- - 0,5-2,30; the carrier is the rest, while cobalt citrates can be coordinated to molybdenum citrate H4[Mo4(C6H5O7)2O11] and to the 6-molybdocobaltate H3[Co(OH)6Mo6O18].
EFFECT: invention makes it possible to obtain regenerated catalysts whose activity in the hydrotreating of diesel fuel is 100 percent or more of the activity of fresh catalysts.
3 cl, 2 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING HYDROTREATED DIESEL FUEL | 2018 |
|
RU2673480C1 |
METHOD FOR REGENERATION OF DEACTIVATED HYDROTREATING CATALYST | 2016 |
|
RU2627498C1 |
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RU2674156C1 |
METHOD FOR REGENERATING DEACTIVATED CATALYST FOR HYDRO-TREATING | 2018 |
|
RU2674157C1 |
METHOD OF DIESEL FUEL HYDROCLEANING | 2016 |
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RU2622040C1 |
HYDROTREATING METHOD OF DIESEL FUEL | 2020 |
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RU2724613C1 |
METHOD OF HYDROTREATING CATALYST REACTIVATION | 2020 |
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RU2725629C1 |
REACTIVATED HYDROTREATING CATALYST | 2020 |
|
RU2731459C1 |
METHOD OF RECOVERING ACTIVITY OF A ZEOLITE-CONTAINING CATALYST | 2019 |
|
RU2714677C1 |
REGENERATED CATALYST FOR HYDROFINING HYDROCARBON MATERIAL, METHOD OF REGENERATING DEACTIVATED CATALYST AND PROCESS OF HYDROFINING HYDROCARBON MATERIAL | 2012 |
|
RU2484896C1 |
Authors
Dates
2017-06-09—Published
2016-08-22—Filed