FIELD: electricity.
SUBSTANCE: separate segments of low-, medium- and high-temperature thermoelectric materials are formed and connected together. The low-temperature segments of the branch of n- and p- conductivity type are formed from two sections by the method of spark plasma sintering. Tellurides of bismuth and selenium of Bi2Te2.7Se0.3 and Bi2Te2.85Se0.15 compounds are used as materials for n-type sections. Tellurides of bismuth and stibium of Bi0.4Sb1.6Te3 and Bi0.27Sb1.3Te3 compounds obtained by hot extrusion are used as materials for p-type sections. The combination of low-temperature sections of n- and p-type is carried out in a graphite mould in a spark plasma sintering unit in a vacuum of ~0.1 Pa with an increase in temperature from room temperature to 400-450°C for 1 minute with holding at this temperature for 5-10 minutes at a pressure of 0.5 MPa and then cooling to room temperature at a speed of 3°C/min.
EFFECT: increased efficiency of the thermoelement.
3 cl, 1 tbl
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Authors
Dates
2017-07-04—Published
2016-09-29—Filed