FIELD: chemistry.
SUBSTANCE: electrosynthesis is carried out under deaerated conditions at the hydrogen sulfide reduction potential on a platinum cathode.
EFFECT: reducing power consumption for electrosynthesis of cyclohexanthiol due to lower electrolysis potential due to a more pronounced tendency of hydrogen sulfide to cathodic activation compared to anodic activation, decreasing the yield of dicyclohexyl disulphide due to the generation of atomic hydrogen in the electrochemical system and exclusion of the oxidation stage of cyclohexanthiol as the desired reaction product.
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Authors
Dates
2017-11-03—Published
2016-06-02—Filed