FIELD: chemistry.
SUBSTANCE: invention relates to field of organic chemistry, in particular, to methods of obtaining element sulphur from hydrogen sulfide-containing gases and gaseous condensate mixtures, and can be applied at enterprises of chemical, petrochemical, gas-processing and metallurgical industry. Method of obtaining element sulphur from hydrogen sulfide includes carrying out hydrogen sulfide electrolysis on platinum anode in organic solvent in presence of background electrolyte at temperature 20-25°C and atmospheric pressure. Before carrying out hydrogen sulfide electrolysis triethylamine is preliminarily introduced into organic solvent.
EFFECT: improvement of the process of obtaining element sulphur, which makes it possible to considerably reduce value of anode overvoltage in carrying out sulphur electrosynthesis basing on hydrogen sulfide Conversion of hydrogen sulfide into element sulfur constitutes 95-98%.
1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| ELECTROCATALYTIC METHOD OF PRODUCING ELEMENTARY SULPHUR FROM HYDROGEN SULPHIDE | 2012 |
|
RU2498938C1 |
| METHOD OF CYCLOHEXANTIOL ELECTROSYNTHESIS BASED ON HYDROGEN SULFIDE | 2016 |
|
RU2634732C1 |
| ELECTROCHEMICAL METHOD OF PRODUCING ORGANIC POLYSULPHANS | 2015 |
|
RU2614151C2 |
| METHOD OF OBTAINING THIOPHEN AND 2-MERCAPTOTHIOPHEN IN ORGANIC SOLVENTS | 2007 |
|
RU2340609C1 |
| ELECTROCHEMICAL METHOD OF OBTAINING CYCLOHEXANETHIOL IN ORGANIC SOLVENTS | 2013 |
|
RU2550141C1 |
| ELECTROCHEMICAL METHOD OF PRODUCING 3,7-DIAMINOPHENOTHIAZINE | 2011 |
|
RU2479674C1 |
| METHOD OF QUANTATIVE DETERMINATION OF POLYSULPHONS IN GASEOUS SULPHUR | 2006 |
|
RU2378644C2 |
| METHOD OF QUANTITATIVE DETERMINATION OF CONCENTRATION OF MERCAPTANS IN NON-AQUEOUS MEDIA | 2002 |
|
RU2207559C1 |
| PROCESS OF QUANTITATIVE DETERMINATION OF HYDROGEN SULFIDE IN NON-AQUEOUS MEDIA | 1997 |
|
RU2167417C2 |
| CATALYTIC PROCESS FOR PREPARING THIOPHENE AND 2-THIOPHENE-THIOL | 2014 |
|
RU2564675C1 |
