FIELD: chemistry.
SUBSTANCE: invention relates to an electrochemical method of obtaining cyclohexanethiol in organic solvents. The method includes the interaction of cyclohexane with hydrogen sulphide under atmospheric pressure, with carrying out a one-stage reaction of cyclohexane with hydrogen sulphide under electrolysis conditions with the potential of hydrogen sulphide oxidation in an organic solvent, in which supporting electrolyte is placed, without the application of a catalyst or a specific reagent at a temperature of the process of 20-25°C.
EFFECT: application of the claimed method makes it possible to obtain the target product with high selectivity and relatively large output under atmospheric pressure without the application of the specific catalyst.
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Authors
Dates
2015-05-10—Published
2013-10-29—Filed