CATALYTIC COMPOSITIONS FOR SELECTIVE DIMERIZATION OF ETHYLENE Russian patent published in 2018 - IPC B01J31/02 C07C2/30 C08F110/02 C08F4/651 C08F4/64 C08F210/16 

Abstract RU 2640820 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst composition for the dimerization of ethylene, comprising: titanate of the formula Ti(OR)4, where R is the same or different and each R is a hydrocarbon residue, where the hydrocarbon residue is an alkyl group or an aryl group; a catalytic additive, wherein the catalytic additive is a simple dibutyl ether, an aromatic ether of the formula R1OR2, where R1 and R2 are the same or different and each is a substituted or unsubstituted C6-15 aromatic group, or a combination thereof; a catalyst modifier, where the catalyst modifier is an amine catalyst modifier or an additional ether catalyst modifier, which differs from the dibutyl ether and aromatic ether, where the catalyst additive and the further catalyst modifier are present in a molar ratio of about 1:5 to about 5:1, and an organoaluminum compound. The invention also relates to a method of producing a catalyst composition, a method of producing an alpha-olefin, and a method of producing a product for further processing thereof.

EFFECT: improved output and activation time.

15 cl, 7 dwg, 5 tbl, 6 ex

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RU 2 640 820 C1

Authors

Schmidt Roland

Al-Hazmi Mohammed H.

Al-Anazi Mohammed F.

Pradhan Devranjan J.

Dates

2018-01-18Published

2014-12-12Filed