CATALYTIC COMPOSITIONS FOR SELECTIVE DIMERIZATION AND POLYMERIZATION OF ETHYLENE Russian patent published in 2018 - IPC B01J31/02 C07C2/30 C08F110/02 C08F4/651 C08F4/64 C08F210/16 

Abstract RU 2640821 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a catalyst composition for the polymerization of alkene, comprising: titanate of the formula Ti(OR)4, wherein all R are the same or different and each R is a hydrocarbon residue, wherein the hydrocarbon residue is an alkyl group or an aryl group; a modifier-catalyst on the basis of simple ether and iluminacin, iluminacin is methylaluminoxane modified methylaluminoxane or a combination thereof, and an additional organoaluminum compound, which is different from methylaluminoxane and modified methylaluminoxane, wherein the modified methylaluminoxane is a copolymer containing repeating units of MeAlO and repeating links R3AlO, where R3 denotes C2-12 of the hydrocarbon residue. The invention also relates to a method for synthesis of the said compounds.

EFFECT: catalyst has improved viability and initiation time.

14 cl, 3 ex, 3 tbl, 2 dwg

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RU 2 640 821 C1

Authors

Schmidt Roland

Al-Hazmi Mohammed H.

Al-Anazi Mohammed F.

Pradhan Devranjan J.

Dates

2018-01-18Published

2014-12-12Filed