FIELD: technological processes.
SUBSTANCE: group of inventions relates to zeolite-containing materials and their use as catalysts. Catalyst for the non-hydrogen de-waxing of a hydrocarbon feedstock, in particular diesel fuel, based on a granular mixture of ZSM-5 aluminosilicate zeolite with a SiO2/Al2O3, equal to 23–80, with a binder (Al2O3 or SiO2), modified by zinc fluoride to 1.5–5.0 % zinc, characterized by a residual content of sodium ions of less than 0.1 % is proposed. Zinc fluoride modification is carried out in two steps – ion exchange in an aqueous solution of a zinc salt, then the resulting zinc zeolite form is treated with an aqueous solution of ammonium fluoride, wherein the said modification is carried out twice. Method of dewaxing a hydrocarbon feedstock using the inventive catalyst is also provided.
EFFECT: implementation of the proposed group of inventions provides increased activity and stability of the catalyst, an increase in the yield of a qualitative target product in the dewaxing of raw materials with an increase in process productivity.
5 cl, 2 tbl, 6 ex
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CATALYST, METHOD OF ITS USE AND INSTALLATION FOR ANTI-WASTE DEPARAFINIZATION OF HYDROCARBON RAW MATERIAL | 2016 |
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CATALYST, METHOD OF MANUFACTURING THEREOF AND PROCESS OF DIESEL FUEL HYDROISOMERISATION | 2013 |
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METHOD FOR OBTAINING HIGH-OCTANE GASOLINE AND/OR AROMATIC HYDROCARBONS WITH LOW BENZENE CONTENT | 2009 |
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CATALYST AND METHOD FOR HYDROISOMERISATION OF NORMAL C5-C8 HYDROCARBONS USING SAID CATALYST | 2017 |
|
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COMPOSITION FOR HYDROCARBON CONVERSION CATALYST | 2011 |
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RU2581043C2 |
ZEOLITE-CONTAINING CATALYST, METHOD FOR PRODUCTION THEREOF AND METHOD OF CONVERTING C-C ALIPHATIC HYDROCARBONS AND METHANOL TO HIGH-OCTANE GASOLINE AND AROMATIC HYDROCARBONS | 2009 |
|
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ZEOLITE-CONTAINING CATALYST, METHOD OF PREPARING SAID CATALYST AND METHOD OF PREPARING ENGINE FUEL USING SAID CATALYST | 2007 |
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RU2382814C2 |
Authors
Dates
2018-03-22—Published
2017-03-06—Filed