FIELD: recycling and disposal of waste.
SUBSTANCE: invention relates to the processing of liquid radioactive solutions, in particular to the curing of highly active solutions containing beryllium and other stable and radioactive elements. As a substance for the immobilization of beryllium from highly active solutions, sodium aluminophosphate glass having the general formula: Na2O-Me(I)2O-BeO-Al2O3-MeXOY-P2O5-BX1OY1-ElX2OY2, where: Me(I) – monovalent metals, with the exception of sodium; Me – multivalent metals, except for beryllium and aluminum; El – non-metals, with the exception of phosphorus and boron; X, X1, X2, Y, Y1, Y2 – stoichiometric coefficients (1, 2, 3, 4, 5, 6, 7); at a content, mass.%: Na2O + Me(I)2O – from 20 up to 27; BeO – from 0,1 up to 5; Al2O3 + MeXOY – from 15 up to 23; P2O5 + B2O3 – from 50 up to 57 (including B2O3 from 0 up to 6); ElX2OY2 – from 0 up to 10.
EFFECT: invention makes it possible to obtain a chemically stable and non-dusting substance capable of including beryllium.
1 cl, 4 tbl
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Authors
Dates
2018-06-20—Published
2017-09-19—Filed