FIELD: processing and recycling of wastes; nuclear engineering.
SUBSTANCE: invention relates to the localization of liquid radioactive waste, in particular to compositions for curing liquid radioactive solutions and pulps by vitrifying them. Alumophosphate glass for immobilisation of radioactive wastes contains sodium oxide, aluminum oxide, phosphorus oxide and impurities of oxides of monovalent and multivalent elements (fission and corrosion products, as well as actinides), as well as a modifying additive, with the following ratio of components, wt%: Na2O – 20.0–25.0, Al2O3 – 13.2–15.5, P2O5 – 48.0–55.0, modifying additive – 2.0–10.0, sum of waste oxides excluding Al2O3, impurities of univalent and multivalent oxide (fission and corrosion products, as well as actinoids) 5.0–10.7.
EFFECT: invention enables to reduce crystallisation effects in aluminophosphate glass with hardened radioactive wastes at thermal action near devitrification temperatures (450–550 °C).
1 cl, 2 tbl
Title | Year | Author | Number |
---|---|---|---|
ALUMOPHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE WASTES | 2017 |
|
RU2668605C1 |
GLASS-FORMING BORON PHOSPHATE COMPOUND FOR IMMOBILIZATION OF ALUMINUM-CONTAINING LIQUID HIGH-RADIOACTIVE WASTES | 2004 |
|
RU2267178C1 |
SILICOPHOSPHATE GLASS FOR IMMOBILISING RADIOACTIVE WASTES | 2008 |
|
RU2386182C2 |
SUBSTANCE FOR IMMOBILIZATION OF BERYLLIUM CONTAINED IN HIGH-ACTIVE SOLUTIONS | 2017 |
|
RU2658329C1 |
GLASS-FORMING PHOSPHATE COMPOUND FOR IMMOBILIZING HIGH-ACTIVITY ALUMINUM-CONTAINING LIQUID WASTES | 2001 |
|
RU2203513C2 |
MONOLITHIC SILICATE GLASS BLOCK FOR IMMOBILIZING LIQUID RADIOACTIVE WASTES AND ITS MANUFACTURING PROCESS | 2002 |
|
RU2232440C2 |
PREPARATION METHOD OF LIQUID HIGH-ACTIVE WASTE FOR VITRIFICATION | 2009 |
|
RU2432630C2 |
LIQUID RADIOACTIVE WASTE IMMOBILIZING PROCESS | 2005 |
|
RU2293385C1 |
SILICATE MATRIX FOR CONDITIONING RADIOACTIVE WASTES | 2005 |
|
RU2302048C2 |
LOCALISATION OF WASTES BY VITRIFICATION IN METAL CONTAINERS | 2009 |
|
RU2523844C2 |
Authors
Dates
2019-10-02—Published
2019-04-03—Filed