FLUORINATION OF ACRYLATE ESTERS AND DERIVATIVES Russian patent published in 2018 - IPC C07C255/30 C07C255/03 C07C253/30 C07C253/32 C07C67/22 C07C69/24 

Abstract RU 2662159 C1

FIELD: chemistry.

SUBSTANCE: present invention relates to methods for converting acrylic acid esters or their derivatives to difluoropropionic acid or its derivatives. Process for preparation of 2,3-difluoropropionic acid derivatives comprises forming a reaction mixture comprising a fluorocarbon or fluorocarbon solvent, fluorine gas and a compound of formula 5 to form a compound of formula 6, and bringing the compound of formula 6 into contact with an alcohol and a catalyst; wherein reaction mixture contains at least about 50 % of a compound of formula 6 based on the number of moles of the compound of formula 5 added to the reaction mixture. substance 5; substance 6.

EFFECT: method allows to obtain intermediate product with a maximum yield and minimization of adverse reactions.

18 cl, 9 ex, 7 tbl

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RU 2 662 159 C1

Authors

Mu, Yongqi

Dates

2018-07-24Published

2012-06-27Filed