FIELD: technological processes.
SUBSTANCE: three versions of the method for preparing a catalyst for hydrotreating petroleum fractions in sulphide form are proposed. One of the variants of the method for preparing a catalyst for hydrotreating petroleum fractions in sulfide form is carried out by co-extrusion molding a mixture of aluminum hydroxide, molybdenum oxide and basic nickel or cobalt carbonate into cylindrical granules, drying and calcining followed by impregnation with an aqueous solution of thiourea with a concentration of 42–55 wt.% or an aqueous solution of ammonium rhodanate with a concentration of 42–55 wt.%, heat treatment at a temperature of 250–320 °C in a stream of hydrogen for 30–60 minutes; catalyst is obtained containing, in wt.%: nickel sulfide or cobalt sulfide 3.0–8.5, molybdenum sulfide 8.9–22, alumina else.
EFFECT: simplifying the preparation and increasing the catalytic activity of the catalyst, which ensures high activity in hydrodesulfurization reactions during the hydrotreatment of diesel fuel fractions, catalytic cracking feedstock – vacuum gas oil, with a sulfur content of less than 350 ppm, and high activity in hydrodesulfurization reactions in the process of hydrotreating a gasoline fraction with a degree of purification in sulfur from 99½ to 99,8 rel%, in olefins from 95,2 to 98,1 rel%.
3 cl, 2 tbl, 18 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR HYDROFINING DIESEL FRACTIONS | 2014 |
|
RU2596830C2 |
METHOD FOR OBTAINING A CATALYST FOR HYDRAULIC CLEANING OF DIESEL FRACTIONS AND A CATALYST OBTAINED BY THIS METHOD | 2018 |
|
RU2684422C1 |
CATALYST OF OIL FRACTIONS HYDROFINING AND METHOD OF CATALYST PREPARATION | 1998 |
|
RU2147255C1 |
METHOD OF PRODUCING CATALYTIC COMPOSITION | 2006 |
|
RU2417124C2 |
METHOD OF ACTIVATING CATALYST OF OIL FRACTION HYDROPURIFICATION | 2008 |
|
RU2352394C1 |
METHOD OF PREPARING CATALYSTS AND CATALYST FOR DEEP HYDROFINING OIL FRACTIONS | 2012 |
|
RU2486010C1 |
CATALYTIC CRACKING GASOLINE HYDROTREATING CATALYST AND A METHOD FOR PRODUCTION THEREOF | 2019 |
|
RU2708643C1 |
CATALYST OF DEEP HYDRODESULFURIZATION OF VACUUM GASOIL AND METHOD OF ITS PREPARATION (VARIANTS) | 2018 |
|
RU2666733C1 |
CATALYST OF DEEP HYDROTREATMENT OF OIL FRACTIONS AND METHOD OF ITS PREPARATION | 2012 |
|
RU2497586C2 |
METHOD TO PRODUCE CATALYST FOR HYDROCLEANING OIL RAWS | 1992 |
|
RU2022644C1 |
Authors
Dates
2019-01-16—Published
2018-09-20—Filed