FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing a catalyst for selective catalytic reduction (SCR) and an SCR-active, iron-containing molecular sieve. Method of producing active in reaction selective catalytic reduction (SCR-active) catalyst based on molecular sieve includes performing hydrothermal treatment of iron-containing molecular sieve in non-oxidising atmosphere at temperature in range from 600 °C to 900 °C for 15 minutes to two hours. Molecular sieve is a zeolite having structure AEI, AFX, CHA, FER or SFW. SCR-active iron molecular sieve of structure AEI, AFX, CHA, FER or SFW is a molecular sieve, hydrothermally treated in steam containing non-oxidising atmosphere at temperature in range from 600 °C to 900 °C for 15 minutes to two hours. Said molecular sieve shows such selective catalytic reduction of nitrogen oxides with NH3 ammonia or urea at temperature of 250 °C, which is at least 50 % more than for comparable iron-containing molecular sieve which has been calcined at temperature of 500 °C for two hours without performing hydrothermal treatment in a non-oxidising atmosphere.
EFFECT: catalyst has improved low-temperature efficiency.
8 cl, 5 dwg, 1 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
NEW MICROPOROUS CRYSTALLINE MATERIAL INCLUDING MOLECULAR SIEVES OR ZEOLITE WITH OCTO-RING STRUCTURE OF OPEN PORES AND METHODS OF ITS PRODUCTION AND APPLICATION | 2008 |
|
RU2445166C2 |
CATALYTIC FILTER FOR EXHAUST GAS PROCESSING | 2012 |
|
RU2649005C2 |
NOX TRAP COMPOSITION | 2014 |
|
RU2674020C2 |
CATALYST FOR TREATING NON-STATIONARY NO EMISSIONS | 2010 |
|
RU2582341C2 |
CATALYTIC FILTER WITH FLOW WALLS WITH CATALYST FOR NEUTRALIZING AMMONIA SLIP | 2018 |
|
RU2755135C2 |
CATALYSTS FOR TREATING NON-STATIONARY NO EMISSIONS | 2012 |
|
RU2586685C2 |
CATALYST FOR TREATING EXHAUST GAS | 2012 |
|
RU2640411C2 |
ZEOLITE CATALYST INCLUDING METAL | 2011 |
|
RU2614411C2 |
ZONED CATALYTIC FILTERS FOR CLEANING EXHAUST GAS | 2012 |
|
RU2609476C2 |
OXIDATION CATALYST FOR INTERNAL COMBUSTION ENGINE OPERATING ON LEAN MIXTURE | 2011 |
|
RU2577856C2 |
Authors
Dates
2019-10-15—Published
2015-02-27—Filed