FIELD: medicine.
SUBSTANCE: invention relates to dentistry, specifically to a photocurable composition as a dental composite resin, which contains a polymerizable (meth)acrylate monomer and a photopolymerization initiator which contains: a photosensitizer – α-diketone; aromatic tertiary amine of formula (1) , where substituents R1 and R2 independently of each other represent C1-C6 alkyl, C1-C6 haloalkyl or C1-C6 hydroxyalkyl group, and substitute R3 is C1-C6 alkyl, C2-C12 alkenyl, C1-C10 alkoxy or C1-C10 alkyloxycarbonyl group; and aryliodonium salt, in which arylydonionium cation is selected from diphenyliodonium, bis(p-chlorophenyl)iodonium, ditolyliodonium, bis(p-methoxyphenyl)iodonium, bis(p-tert-butylphenyl)iodonium, p-isopropylphenyl-p-methylphenyliodonium, bis(m-nitrophenyl)iodonium, p-tert-butylphenylphenyliodonium, p-methoxyphenylphenyliodonium, p-octyloxyphenylphenyliodonium or p-phenoxyphenylphenyliodonium, and the counterion is selected from nitrate-, acetate-, chloroacetate-, carboxylate- or phenolate-anion.
EFFECT: invention provides improved hardening of the composition when exposed to active light to obtain a hardened material having high strength.
6 cl, 3 tbl, 27 ex
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Authors
Dates
2019-12-17—Published
2017-03-08—Filed