FIELD: medicine.
SUBSTANCE: invention relates to dentistry, specifically to a photocurable composition as a dental composite resin, which contains a polymerizable (meth)acrylate monomer and a photopolymerization initiator which contains: a photosensitizer – α-diketone; aromatic tertiary amine of formula (1)  , where substituents R1 and R2 independently of each other represent C1-C6 alkyl, C1-C6 haloalkyl or C1-C6 hydroxyalkyl group, and substitute R3 is C1-C6 alkyl, C2-C12 alkenyl, C1-C10 alkoxy or C1-C10 alkyloxycarbonyl group; and aryliodonium salt, in which arylydonionium cation is selected from diphenyliodonium, bis(p-chlorophenyl)iodonium, ditolyliodonium, bis(p-methoxyphenyl)iodonium, bis(p-tert-butylphenyl)iodonium, p-isopropylphenyl-p-methylphenyliodonium, bis(m-nitrophenyl)iodonium, p-tert-butylphenylphenyliodonium, p-methoxyphenylphenyliodonium, p-octyloxyphenylphenyliodonium or p-phenoxyphenylphenyliodonium, and the counterion is selected from nitrate-, acetate-, chloroacetate-, carboxylate- or phenolate-anion.
, where substituents R1 and R2 independently of each other represent C1-C6 alkyl, C1-C6 haloalkyl or C1-C6 hydroxyalkyl group, and substitute R3 is C1-C6 alkyl, C2-C12 alkenyl, C1-C10 alkoxy or C1-C10 alkyloxycarbonyl group; and aryliodonium salt, in which arylydonionium cation is selected from diphenyliodonium, bis(p-chlorophenyl)iodonium, ditolyliodonium, bis(p-methoxyphenyl)iodonium, bis(p-tert-butylphenyl)iodonium, p-isopropylphenyl-p-methylphenyliodonium, bis(m-nitrophenyl)iodonium, p-tert-butylphenylphenyliodonium, p-methoxyphenylphenyliodonium, p-octyloxyphenylphenyliodonium or p-phenoxyphenylphenyliodonium, and the counterion is selected from nitrate-, acetate-, chloroacetate-, carboxylate- or phenolate-anion.
EFFECT: invention provides improved hardening of the composition when exposed to active light to obtain a hardened material having high strength.
6 cl, 3 tbl, 27 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| PHOTO-CURED COMPOSITION AND DENTAL FILLING MATERIAL | 2018 | 
 | RU2753531C2 | 
| PHOTOCURABLE COMPOSITION, DENTAL PROSTHESIS REPAIR MATERIAL AND KIT FOR THEIR PRODUCTION | 2019 | 
 | RU2768151C1 | 
| CURABLE DENTISTRY COMPOSITION | 2020 | 
 | RU2821202C1 | 
| SET OF FILLING RESTORATION MATERIALS | 2020 | 
 | RU2821271C1 | 
| CURABLE COMPOSITION | 2018 | 
 | RU2759435C2 | 
| DENTAL BLANK FOR MILLING AND METHOD OF ITS PRODUCTION | 2020 | 
 | RU2807748C2 | 
| SUBSTITUTED SACCHARIDE COMPOUNDS AND DENTAL COMPOSITIONS | 2011 | 
 | RU2605097C2 | 
| DENTAL ADHESIVE | 2023 | 
 | RU2822935C1 | 
| CURABLE COMPOSITION AND DENTAL FILLING MATERIAL | 2016 | 
 | RU2724903C2 | 
| TWO-COMPONENT DENTAL ADHESIVE PRODUCT | 2017 | 
 | RU2717311C1 | 
Authors
Dates
2019-12-17—Published
2017-03-08—Filed