FIELD: chemical or physical processes.
SUBSTANCE: group of inventions relates to a selective catalytic reduction (SCR) system and methods of reducing emissions of nitrogen oxides in waste gases. System can operate continuously with SCR catalyst at low temperatures (250–350 °C) with waste gas with high content of SOx (20 ppm or higher) without deactivation due to formation of ammonium bisulphate and/or with improved NOx removal efficiency at low temperatures. SCR system for continuous urea-based operation includes a source of a solution containing urea and at least one NO2-forming compound, where at least one compound which forms NO2 contains: metal nitrate salt; mixture of a compound containing metal nitrate, and N2O4, N2O5 or mixture thereof; SCR catalyst; and a device for introducing solution from a source of solution into a stream of waste gas, before the exhaust gas comes into contact with the SCR catalyst.
EFFECT: group of inventions provides continuous operation of urea-based SCR system at low temperatures, operation in presence of waste gas with high content of SOx.
11 cl, 1 ex, 1 tbl, 3 dwg
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OXIDATION CATALYST FOR INTERNAL COMBUSTION ENGINE EXHAUST GAS TREATMENT | 2012 |
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Authors
Dates
2020-06-25—Published
2016-01-29—Filed