ALKANE OXIDATION TO ALKENE Russian patent published in 2020 - IPC C07C5/42 C07C11/04 C07C11/06 C07C11/08 C07C15/46 C07C1/20 C07C29/03 C07C31/10 

Abstract RU 2733408 C1

FIELD: chemistry.

SUBSTANCE: invention relates to a method of converting an alkane into an alkene. Method comprises: (a) contacting an alkane and (i) an oxidising electrophile, having a base group element selected from gallium, germanium, arsenic, tin, thallium, lead, antimony, selenium, tellurium, bismuth or iodine, in an oxidised form, or (ii) an oxidising agent and a reduced form of an oxidising electrophile in a liquid medium containing an oxygenic acid to obtain an oxidised intermediate and a reduced form of an oxidising electrophile; and (b) carrying out an elimination reaction for the oxidised intermediate to obtain an alkene and an oxygenic acid.

EFFECT: disclosed method is low-temperature, wherein results in high conversion and / or high selectivity with respect to the desired product.

21 cl, 5 ex, 7 dwg

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RU 2 733 408 C1

Authors

Periana, Roy, A.

Hashiguchi, Brian, G.

Konnick, Michael, M.

Dates

2020-10-01Published

2018-05-25Filed