METHOD OF PRODUCING COMPLEXES OF RUTHENIUM AND INTERMEDIATE COMPOUNDS THEREOF AND USE THEREOF IN METATHESIS OF OLEFINS Russian patent published in 2020 - IPC C07F15/00 B01J31/22 B01J37/04 C07C67/333 C07C69/533 C07C69/74 

Abstract RU 2735724 C1

FIELD: chemical or physical processes.

SUBSTANCE: present invention relates to a method of producing a compound of formula 1, ,

where the substituent values are as defined in the claim. Method involves contacting an alkylidene ruthenium complex represented by formula 2, , with carbene represented by formula 3, , then formed reaction mixture is brought into contact with compound of formula 4, , to obtain a compound represented by formula 1. Also disclosed are a compound of formula 1, an intermediate compound of formula 5, use of compounds of formula 1 and formula 5. Method of the present invention enables avoiding complex synthesis of the complex and enables simple modification of the benzylidene ligand.

EFFECT: obtained compounds have proved to be excellent catalysts for olefin metathesis.

20 cl, 7 tbl, 49 ex, 4 dwg

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RU 2 735 724 C1

Authors

Skowerski, Krzystof

Rafal, Gawin

Dates

2020-11-06Published

2016-07-27Filed