FIELD: chemistry.
SUBSTANCE: invention relates to methods for obtaining monomers containing a sulphuric acid group. Proposed is a method for obtaining a monomer containing a sulphuric acid group by the formula CF2=CFO(CFX)nSO3Y is proposed, including the stage of combining and stirring a cyclic compound by the general formula (1) and a silanol compound by the general formula R1R2R3Si(OM), wherein X constitutes F or CF3, and n is an integer from 1 to 6, wherein when n is greater than or equal to 2, all CFX can be the same or different; M constitutes an alkali metal or alkaline earth metal; and each of R1 to R3 independently constitutes an optionally substituted hydrocarbon group with 1 to 10 carbon atoms, or OM, where M is an alkali or alkaline earth metal.
EFFECT: proposed method allows obtaining a monomer containing a sulphuric acid group with high yield, usable as a raw material for fluorine-based polymer electrolytes, such as membranes for fuel elements, catalytic binding polymers for fuel elements, and membranes for chlor-alkali electrolysis.
4 cl, 8 ex
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Authors
Dates
2021-07-08—Published
2019-02-13—Filed