FIELD: energy storage.
SUBSTANCE: present invention relates to modified red sludge/modified bauxite residue, as well as a method for obtaining it and an energy storage device containing modified red sludge, a heat storage device containing an energy storage device, and methods for using modified red sludge as an energy storage device, in particular, as part of a heat storage device. Modified red sludge contains following components: hematite (Fe2O3), corundum (Al2O3), rutile (TiO2) and/or anatase (TiO2), quartz (SiO2), in some cases perovskite (CaTiO3) and in some cases pseudobrucite ((Fe3+,Fe2+)2(Ti,Fe3+)O5), nepheline ((Na,K)[AlSiO4]) and/or gayuinite ((Na,Ca)4-8[Al6Si6O24(SO4)]). At the same time, modified red sludge contains Na2O and/or glass, in amount of less than 0.5% by weight of Na2O and/or glass. Modified red sludge has a particle size d10 in the range of 0.5 to 2.5 mcm and/or a particle size d90 in the range of 15 to 50 mcm. Red sludge is washed with water containing iron (II) chloride, dried, then heated to a temperature of at least 800°C, preferably at least 1000°C or 1150°C.
EFFECT: achieved technical result is an increase in the service life during operation in the temperature range up to 1000°C.
37 cl, 5 tbl, 4 dwg, 3 ex
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Authors
Dates
2021-08-23—Published
2017-09-01—Filed