FIELD: polymer chemistry.
SUBSTANCE: method for producing complex stabilizers of polyvinyl chloride, and can be used in processing compositions of chlorine-containing polymers into various products (film materials, cable plastic compounds, profiles, building materials, pipes, etc.). The method is implemented by reacting monocarboxylic acids in an amount of 0.5 mol with a mixture of Ba, Zn or Ca oxides in the presence of a phenolic antioxidant and an ester plasticizer when heated to 130-150°C until the acid number reaches no more than 5 mg KOH/g at the first stage. Then a residual amount of monocarboxylic acid in the amount of 0.2 mol and glycerol are added to the reaction mass and synthesis is carried out at a temperature of 165°C until the acid number reaches 5-10 mg KOH/g. Then the reaction mass is cooled to 40-45°C, epoxidized soybean oil, polyglycerin, and NF phosphite are added, and the resulting mixture is stirred for 20 minutes.
EFFECT: expansion of the range of non-toxic complex stabilizers and improvement in physical and mechanical properties of polymer materials.
4 cl, 1 tbl, 29 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING COMPLEX STABILISERS FOR CHLORINE-CONTAINING POLYMERS | 2008 |
|
RU2400496C2 |
COMPOSITE ESTER COMPOUND, PLASTICIZING COMPOSITION BASED ON IT, METHOD FOR PRODUCTION OF PLASTICIZING COMPOSITION, AND PVC-COMPOSITION CONTAINING COMPOSITE ESTER COMPOUND OR PLASTICIZING COMPOSITION | 2020 |
|
RU2776848C2 |
METHOD FOR OBTAINING ALKENYL CYANOETHYL SUCCINIMIDES OF 1,2-DISUBSTITUTED IMIDAZOLINE | 2017 |
|
RU2670452C1 |
METHOD OF OBTAINING COMPLEX STABILIZERS OF POLYVINYL CHLORIDE | 0 |
|
SU601276A1 |
PLASTICIZING COMPOSITION OF POLYFUNCTIONAL ACTION FOR CHLORINE-CONTAINING POLYMERS AND ITS PRODUCTION METHOD | 2020 |
|
RU2762325C1 |
METHOD OF PRODUCING METAL-CONTAINING LUBRICANT FOR PVC COMPOSITION | 2017 |
|
RU2644898C1 |
GROWTH STIMULATING AGENT FOR PRE-SOWING SEED TREATMENT | 2020 |
|
RU2746139C1 |
METHOD OF PRODUCING METAL-CONTAINING LUBRICANTS FOR PVC COMPOSITION | 2017 |
|
RU2642075C1 |
PROCESS FOR PREPARING $$$-BROMOISOVALERIC ACID ETHYL ESTER | 1993 |
|
RU2080318C1 |
METAL CORROSION INHIBITOR | 2000 |
|
RU2178015C1 |
Authors
Dates
2023-11-07—Published
2022-07-18—Filed