FIELD: various technological processes.
SUBSTANCE: invention relates to high-temperature catalytic oxidative methods of converting methane to produce synthesis gas. Disclosed is a method of producing synthesis gas by high-temperature catalytic oxidative conversion of methane by supplying an initial gas mixture containing a mixture of methane and carbon dioxide, into reactor with complex oxide catalyst at high temperature, characterized by that the catalyst used is a complex cobalt and samarium oxide obtained by mixing initial cobalt and samarium compounds, taken in stoichiometric ratios corresponding to the cobalt content in the product after calcination equal to 2 wt.%, with calcination of obtained mixture at temperature increase from room temperature to 800 °C for 3 hours and held at this temperature for 2 hours to obtain a complex oxide of cobalt and samarium, located in a vertical reactor on a substrate of quartz fibre, before the catalyst, a small amount of quartz chips is placed, which acts as a gas mixer, the catalyst is heated in a stream of nitrogen to 900 °C, after which nitrogen supply is switched off and a mixture of methane and carbon dioxide is supplied to the reactor, while maintaining the temperature of catalyst at 900 °C during the entire process of oxidative conversion of methane.
EFFECT: development of a method of producing synthesis gas by carbon dioxide conversion of methane, which provides higher efficiency of the catalyst and yields of CO and H2, as well as providing fast catalyst output to its optimum operating mode.
3 cl, 1 tbl, 32 ex
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Authors
Dates
2024-02-28—Published
2023-05-25—Filed