FIELD: chemistry.
SUBSTANCE: invention relates to methods of producing light olefins by cracking propane, which is a component of associated petroleum gas (APG), using catalysts based on neodymium molybdate Nd2(MoO4)3 and ytterbium molybdate Yb2(MoO4)3 with content of 0.10–0.50 wt.% of dopant of sodium ions obtained from neodymium nitrate hexahydrate Nd(NO3)3⋅6H2O or ytterbium nitrate hexahydrate Yb(NO3)3⋅6H2O and sodium molybdate dihydrate Na2MoO4⋅2H2O, with subsequent calcination of the obtained precipitate in a muffle furnace at temperature of 700 °C for 3 hours. Method involves bringing the catalysts into contact with propane, which is fed at a volume rate of 1.25 ml/s at temperature of 500±10 °C and pressure of 0.1 MPa.
EFFECT: high conversion of propane and process output for light olefins while maintaining high selectivity; increased service life of the catalyst and simple regeneration, simplified process for the process of catalytic cracking of propane.
1 cl, 3 tbl, 4 ex
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Authors
Dates
2024-05-27—Published
2023-12-12—Filed