FIELD: chemistry.
SUBSTANCE: group of inventions includes a number of ionic compounds, a method for production thereof and use thereof as energy materials. Compound ABX3, AB'X4 or B'2A'X5 consists of cation A or cation A', cation B or cation B' and anion X, where cation A is a divalent nitrogen-containing organic cation; cation B is at least one of alkali metal ions and a monovalent nitrogen-containing cation; cation A' is at least one of alkali metal ions and monovalent nitrogen-containing cation; cation B' is a saturated aliphatic diammonium cation; anion X is selected from at least one of chlorate ion, perchlorate ion, bromate ion, perbromate ion, iodate ion, periodate ion, nitrate ion, fulminate ion, diazenyl group and azide ion. Provided that, if the compound has formula ABX3, cation A is selected from at least one of the ions of Formula (I) and Formula (II) and derivatives thereof, where each n1, n2, n3, n4 and n5 is a positive integer; R1, R2, R3 and R4 are selected from at least one of hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert -butyl, hydroxyl, carbonyl, carboxyl, amino, halogen, mercapto, peroxy, diazenyl and nitro groups; derivatives relate to an organic cationic particle in which hydrogen atoms are substituted, simultaneously or not, substitutes and substitutes include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, hydroxyl, carbonyl, carboxyl, amino, halogen, mercapto, peroxy, diazenyl or nitro,
wherein cation A is selected from at least one of organic cations of formula (I) and derivatives thereof. Any of n1 and n2 is greater than 2 or any of R1 and R2 contains at least one carbon atom; or cation A is selected from at least one of organic cations of formula (II) and derivatives thereof and any of n3, n4 and n5 is greater than 2 or any of R3 and R4 contains at least one carbon atom.
EFFECT: implementation of the purpose is provided.
49 cl, 18 tbl, 40 dwg
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Authors
Dates
2024-08-26—Published
2021-01-21—Filed