FIELD: chemistry.
SUBSTANCE: present invention relates to an ethylene polymer, as well as an article containing an ethylene polymer, and a polymerisation method. Ethylene polymer has density from 0.952 g/cm3 to 0.965 g/cm3, high shear stress melt index (HLMI) from 5 to 25 g/10 min, weight average molecular weight from 275,000 to 450,000 g/mol, number average molecular weight from 15,000 to 28,000 g/mol, viscosity at HLMI from 1400 to 4000 Pa⋅c and tan δ at 0.1 s-1 from 0.65 to 0.98°. Polymerisation method involves bringing the catalyst composition into contact with ethylene and alpha-olefin in a polymerisation reactor system under polymerisation conditions to obtain an ethylene polymer. Catalyst composition contains a non-bridged metallocene compound, a bridged metallocene compound, an activator support and an organoaluminium compound.
EFFECT: obtained polymers have technological characteristics of ethylene polymers obtained using a chromium-based catalyst system but have improved resistance to stress cracking and can be used in blow moulding large parts.
10 cl, 3 dwg, 4 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
BLOW MOULDING POLYMERS TREATED WITH PEROXIDE, WITH INCREASED WEIGHT SWELLING AND CONSTANT SWELLING OF EXTRUDED STREAM | 2022 |
|
RU2829446C2 |
HIGH ESCR POLYMERS FOR USE IN BLOW MOLDING | 2016 |
|
RU2705086C2 |
ETHYLENE HOMOPOLYMERS WITH REVERSE DISTRIBUTION OF SHORT-CHAIN BRANCHES | 2019 |
|
RU2806260C2 |
DUAL CATALYTIC SYSTEM FOR PRODUCING LONG CHAIN BRANCHED HIGH-DENSITY POLYETHYLENES | 2020 |
|
RU2799876C2 |
METALLOCENE DOUBLE ZIEGLER-NATTA CATALYST SYSTEMS WITH ACTIVATORS-CARRIERS | 2016 |
|
RU2730017C2 |
METHODS FOR CONTROLLING DUAL METALLOCENE CATALYST OLEFIN POLYMERIZATIONS WITH AN ALCOHOL COMPOUND | 2014 |
|
RU2655383C2 |
METHODS FOR INCREASING THE COLOR STABILITY OF POLYETHYLENE RESINS | 2018 |
|
RU2775725C2 |
CATALYTIC SYSTEMS BASED ON TITANIUM PHOSPHINIMIDE AND TITANIUM IMINOIMIDAZOLIDIDE WITH ACTIVATOR SUBSTRATES | 2015 |
|
RU2824748C2 |
CATALYTIC SYSTEMS BASED ON TITANIUM PHOSPHINIMIDE AND TITANIUM IMINOIMIDAZOLIDIDE WITH ACTIVATOR-SUPPORTS | 2015 |
|
RU2706120C2 |
DOUBLE CATALYST SYSTEM FOR PRODUCING LLDPE COPOLYMERS WITH IMPROVED PROCESSABILITY | 2018 |
|
RU2740918C1 |
Authors
Dates
2025-01-10—Published
2020-07-20—Filed